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Promotional Effect of Palladium on the Hydrogen Oxidation Reaction at a PtPd Alloy Electrode
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Web of Science
Cited 52 time in Scopus
- Authors
- Issue Date
- 2008-12
- Publisher
- John Wiley & Sons Ltd.
- Citation
- Angewandte Chemie International Edition, Vol.47 No.48, pp.9307-9310
- Abstract
- (Figure Presented) A volcano curve is observed for the hydrogen oxidation reaction (HOR) as a function of the Pd content of alloyed PtPd electrodes. The maximum exchange current density was obtained for Pt72Pd 28, and the results indicate that PdHx species (hydrogen gas spontaneously adsorbed to Pd; see picture) causes the electronic structure of Pt to be favorable for the HOR. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
- ISSN
- 1433-7851
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Related Researcher
- College of Engineering
- School of Chemical and Biological Engineering
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