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Effect of Lattice Dynamics on Intramolecular Electron-Transfer Rates in Mixed-Valence Complexes

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Authors
Hendrickson, David N.; Oh, Seung M.; Dong, Teng-Yuan; Kambara, Takeshi; Cohn, Michelle J.; Moore, Michael F.
Issue Date
1985-11-01
Publisher
Taylor & Francis
Citation
Comments Iriorg. Chem. 4, 329 (1985)
Abstract
It is shown that the rates of intramolecular electron transfer for mixed-valence complexes in the solid state are not determined only by the electronic and vibronic coupling in the molecular complex. Lattice dynamics associated with the motion of ligands, solvate and counterions, which sometimes are manifested as phase transitions, frequently influence the electron-transfer rate.
ISSN
0260-3594 (print)
1548-9574 (online)
Language
English
URI
https://hdl.handle.net/10371/5639
DOI
https://doi.org/10.1080/02603598508072271

https://doi.org/10.1080/02603598508072271
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
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