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Effect of Interfacial Adhesion on the Mechanical Properties of Organic/Inorganic Hybrid Nanolaminates

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dc.contributor.authorYeom, Bongjun-
dc.contributor.authorKim, Suhan-
dc.contributor.authorCho, Jinhan-
dc.contributor.authorHahn, Junhee-
dc.contributor.authorChar, Kookheon-
dc.date.accessioned2009-07-22T03:31:57Z-
dc.date.available2009-07-22T03:31:57Z-
dc.date.issued2006-06-
dc.identifier.citationJournal of Adhesion 82, 447-468 (2006)en
dc.identifier.issn0021-8464 (print)-
dc.identifier.issn1545-5823 (onlinr)-
dc.identifier.urihttp://hdl.handle.net/10371/5800-
dc.description.abstractTwo different kinds of organic polyelectrolyte (PE)/inorganic silicate nanolaminates carrying dissimilar interfacial adhesion between the organic and the inorganic layers were prepared using the layer-by-layer self-assembly. To investigate the mechanical behavior of the prepared hybrid films, apparent modulus (E'), hardness (H), and crack length were measured by depth-sensing nanoindentation as well as a microVickers experiment. The fracture toughness of the hybrid films was then calculated based on the measured mechanical values. In the case of forming strong interfacial adhesion between the organic and the inorganic layers (A series), the fracture toughness and the crack resistance of hybrid multilayer films were significantly improved as a result of the redistribution of stress concentration and the dissipation of fracture energy by the plasticity of organic PE layers. On the other hand, samples with relatively low interfacial adhesion between the organic and the inorganic layers (T series) had little effect on the improvement of fracture toughness of the hybrid films.en
dc.description.sponsorshipThis work was financially supported by the National Research Laboratory Program (Grant M1-0104-00-0191) and funded in part by the
Ministry of Education through the Brain Korea 21 Programs at Seoul National University. Additionaly, this work was supported by the
SRC=ERC program of MOST=KOSEF (R11-2005-048-00000-0). B. Y. also acknowledges the financial support through the Seoul Science
Fellowship. The X-ray experiments performed at Pohang Light Source were supported by the Ministry of Science and Technology of Korea (MOST).
en
dc.language.isoen-
dc.publisherTaylor & Francisen
dc.subjectFracture toughnessen
dc.subjectInterfacial adhesionen
dc.subjectMechanical propertyen
dc.subjectNacreen
dc.subjectNanoindentationen
dc.subjectOrganic/inorganic hybrid nanolaminateen
dc.titleEffect of Interfacial Adhesion on the Mechanical Properties of Organic/Inorganic Hybrid Nanolaminatesen
dc.typeArticleen
dc.contributor.AlternativeAuthor염봉준-
dc.contributor.AlternativeAuthor김수한-
dc.contributor.AlternativeAuthor조진한-
dc.contributor.AlternativeAuthor한준희-
dc.contributor.AlternativeAuthor차국헌-
dc.identifier.doi10.1080/00218460600713592-
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College of Engineering/Engineering Practice School (공과대학/대학원)Dept. of Chemical and Biological Engineering (화학생물공학부)Journal Papers (저널논문_화학생물공학부)
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