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Change in Quantum Efficiency of Self-assembled Films Based on PPV and Ionic Salt Added PSS

Cited 2 time in Web of Science Cited 2 time in Scopus
Authors

Cho, Jinhan; Char, Kookheon; Hong, Jong-Dal; Kim, Dong Young

Issue Date
2001-10-01
Publisher
Taylor & Francis
Citation
Mol. Cryst. Liq. Cryst., 371, 75
Keywords
poly(p-phenylene vinylene) (PPV)electroluminescence (EL);self-assembly method
Abstract
Electrical characteristics of self-assembled devices based on Poly(p-phenylene vinylene) (PPV), Poly(sodium 4-styrenesulfonate) (PSS) and carrageenan (CARRA) were investigated. Relative quantum efficiency of ITO/(PPV/PSS)20/Al device was significantly decreased with the increase of ionic strength of the PSS solution. In contrast, the relative quantum efficiency of ITO/(PPV/PSS)5/(PPV/CARRA)15/Al device prepared by inserting (PPV/CARRA)15 bilayers between the (PPV/PSS)5 film and Al electrode were increased with the increase of ionic strength in the PSS solution. The performance improvement of ITO/(PPV/PSS)5/(PPV/CARRA)15/Al device is believed to be due to the formation of a stable interface between the (PPV/CARRA) and the Al electrode as well as the enhancement of hole transporting characteristics of (PPV/PSS) bilayers with added ion salt.
ISSN
1542-1406 (print)
1563-5287 (online)
Language
English
URI
https://hdl.handle.net/10371/5854
DOI
https://doi.org/10.1080/10587250108024691
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