Morphology of injection molded modified poly(phenylene oxide)/polyamide-6 blends

Abstract

The morphology of injection molded poly(phenylene oxide)/polyamide-6 blends was investigated. A distinct skin layer, subskin layer, and core region were found across the part thickness, and the morphology of the skin layer was clearly observed. The shape and size of the dispersed phase depended on the position across the part thickness and the viscosity ratio of the component polymers. For low viscosity ratios, small and large particles coexisted in the subskin layer, implying that both coalescence and breakup of the dispersed phase occurred in that layer. For high viscosity ratios, an intermediate zone, in which little deformation of the dispersed phase occurred, was found between the skin layer and the subskin layer. These findings are expected to help foster understanding of the mechanism of morphology evolution during the filling and cooling stages of the injection molding process.