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Synthesis and Properties of Pyrrolidinium and Piperidinium Bis(trifluoromethanesulfonyl)imide Ionic Liquids with Allyl Substituents
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yim, Taeeun | - |
dc.contributor.author | Lee, Hyun Yeong | - |
dc.contributor.author | Kim, Hyo-Jin | - |
dc.contributor.author | Mun, Junyoung | - |
dc.contributor.author | Kim, Sangmi | - |
dc.contributor.author | Oh, Seung M. | - |
dc.contributor.author | Kim, Young Gyu | - |
dc.date.accessioned | 2009-07-30T04:31:45Z | - |
dc.date.available | 2009-07-30T04:31:45Z | - |
dc.date.issued | 2007 | - |
dc.identifier.citation | Bull. Korean Chem. Soc. 2007, 28, 1567 | en |
dc.identifier.issn | 0253-2964 | - |
dc.identifier.uri | http://newjournal.kcsnet.or.kr/main/j_search/j_abstract_view.htm?code=B070922&qpage=j_search | - |
dc.identifier.uri | https://hdl.handle.net/10371/5955 | - |
dc.description.abstract | New pyrrolidinium and piperidinium bis(trifluoromethanesulfonyl)imide (TFSI) ionic liquids (ILs) having
allyl substituents were synthesized and characterized. All of them are liquid at room temperature and stable up to 300 oC. The pyrrolidinium-based ILs showed better conductivities and lower viscosities than the corresponding piperidinium-based ILs. Among them, 1-allyl-1-methylpyrrolidinium TFSI showed the lowest viscosity of 52 cP, the highest conductivity of 5.7 mS cm−1, and the most negative cathodic voltage window of −3.2 V (vs. Fc/Fc+) on a platinum electrode, which are the improved results compared to the corresponding analogue having a saturated substituent, 1-methyl-1-propylpyrrolidinium TFSI. | en |
dc.description.sponsorship | This work was supported by the
Division of Advanced Batteries in NGE Program (Project No. 10016439) and by KOSEF through the Research Center for Energy Conversion and Storage. We also thank BK 21 Project funded by the Ministry of Education and Human Resources Development of Korea. | en |
dc.language.iso | en | - |
dc.publisher | 대한화학회 = The Korean Chemical Society | en |
dc.subject | Ionic liquid | en |
dc.subject | Pyrrolidinium | en |
dc.subject | Piperidinium | en |
dc.subject | Bis(trifluoromethanesulfonyl)imide (TFSI) | en |
dc.subject | Allyl substituent | en |
dc.title | Synthesis and Properties of Pyrrolidinium and Piperidinium Bis(trifluoromethanesulfonyl)imide Ionic Liquids with Allyl Substituents | en |
dc.type | Article | en |
dc.contributor.AlternativeAuthor | 임태은 | - |
dc.contributor.AlternativeAuthor | 이현영 | - |
dc.contributor.AlternativeAuthor | 김효진 | - |
dc.contributor.AlternativeAuthor | 문준영 | - |
dc.contributor.AlternativeAuthor | 김상미 | - |
dc.contributor.AlternativeAuthor | 오승모 | - |
dc.contributor.AlternativeAuthor | 김영규 | - |
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