Publications
Detailed Information
Nanoscale Atoms in Solid-State Chemistry
Cited 189 time in
Web of Science
Cited 194 time in Scopus
- Authors
- Issue Date
- 2013-07
- Citation
- Science, Vol.341 No.6142, pp.157-160
- Abstract
- We describe a solid-state material formed from binary assembly of atomically precise molecular clusters. [Co6Se8(PEt3)(6)][C-60](2) and [Cr6Te8(PEt3)(6)][C-60](2) assembled into a superatomic relative of the cadmium iodide (CdI2) structure type. These solid-state materials showed activated electronic transport with activation energies of 100 to 150 millielectron volts. The more reducing cluster Ni9Te6(PEt3)(8) transferred more charge to the fullerene and formed a rock-salt-related structure. In this material, the constituent clusters are able to interact electronically to produce a magnetically ordered phase at low temperature, akin to atoms in a solid-state compound.
- ISSN
- 0036-8075
- Files in This Item:
- There are no files associated with this item.
Related Researcher
- College of Engineering
- Department of Electrical and Computer Engineering
Item View & Download Count
Items in S-Space are protected by copyright, with all rights reserved, unless otherwise indicated.